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Zeolites

Zeolum® | HSZ® - series


Product Name

Zeolum®

Generic Name

Zeolite molecular sieves

Chemical formula/Diagram

MeO· Al2O3·mSiO2· nH2O
(Me: Metal Ion)

Product Overview

Zeolum® is a synthetic zeolite possessing strong selective adsorption properties. Zeolum® is suitable for drying, purifying and separating a wider variety of feeds than any other adsorbent.

Applications
  1. Gas Production: Separation of nitrogen and oxygen from air, H2 purification in PSA processes, removal of carbon dioxide and moisture from air, purification in cryogenic processes.
  2. Petrochemical Production and Refining: Drying of naphtha cracked gas, drying of organic solutions.
  3. Others: Drying and purification of refrigerants, prevention of cloudiness in multilayer glass, removal of trace moisture from urethane paints and sealants, moisture control in pharmaceutical and food packaging, exhaust gas treatment.

Typical properties/grades

Types Form Grade Size Packing Application




A-3


Beads		   4-8mesh, 8-10mesh 30kg, 150kg  
9-14mesh
RG 8-12mesh 20kg, 150kg R-134a
RH 8-12mesh 30kg R-410A, R-407C
Pellets CGS IV 3mmØ, 1.5mmØ 130kg, 500kg Cracked Gas
Powder   100mesh under 20kg  
A-4 Beads   4-8mesh, 8-10mesh 30kg, 150kg  
9-14mesh 20kg  
Pellets   1.5mmØ 25kg, 125kg  
NGS 3mmØ 500kg Natural Gas
Powder   100mesh under 20kg  
A-5 Beads   4-8mesh 20kg, 150kg  
TMS-4 8-10mesh 25kg, 600kg Natural Gas
Pellets   1.5mmØ 20kg, 130kg  
SA-500 1.5mmØ 500kg PSA
F-9 Beads   4-8mesh 20kg, 140kg  
8-10mesh, 9-14mesh 25kg, 140kg  
Pellets   1.5mmØ 20kg, 125kg  
HA 1.5mmØ 125kg, 500kg Cryogenic
SA-600 1.5mmØ 500kg PSA
Powder   100mesh under 15kg  
Beads NSA 9-14mesh   PSA



For more information, please contact your nearest representative:

TOSOH Corporation TOSOH USA, Inc. TOSOH Europe B.V.
(Headquarters) (Head Office) (Head Office)
Shiba-koen First Bldg., 3600 Gantz Road, Crown Building-South,
3-8-2, Shiba, Minato-ku, Grove City, OH 43123-1895 Hullenbergweg 359,
Tokyo 105-8623, U.S.A. 1101 CP Amsterdam Z.O.,
Japan Tel: 1-614-277-4348 The Netherlands
Tel: 81-3-5427-5173 Tel: 1-866-844-6953 (U.S. Toll Free) Tel: 31-20-565-0010
Fax: 81-3-5427-5217 Fax: 1-614-875-8066 Fax: 31-20-691-5458
e-mail: info@tosoh.co.jp
URL: www.tosoh.com		 e-mail: info.tusa@tosoh.com
URL: www.tosohusa.com		 e-mail: info.tse@tosoh.com
URL: www.tosoh-europe.com


 

Product Name

 

Product Name

HSZ® - series

Generic Name

High Silica Zeolite

Chemical formula/Diagram

MeO· Al2O3· mSiO2· nH2O
(Me: Metal or H ion)

Product Overview

HSZ®-series are high silica zeolites with higher SiO2 / Al2O3 mol ratios than zeolite molecular sieves. HSZ®-series have high thermal and acid stability, making them useful in catalyst and adsorbent applications.

Applications
  • Petroleum refining catalysts
Hydrocracking, isomerization, dewaxing
  • Petrochemical catalysts

Alkylation, isomerization
  • Others:
Hydrocarbon trap in exhaust gas, De - NOx catalysts.

Typical properties/grades

Grade

Type

HSZ® - 300

Y

HSZ® - 500

L

HSZ® - 600

Mordenite

HSZ® - 700

Ferrierite

HSZ® - 900

Beta



HSZ® - 300 Series (USY Zeolite)
  320NAA 320HOA 331HSA 330HUA
Cation Type Na H H H
SiO2/Al2O3 (mol/mol) 5.5 5.5 6 6
Na2O (wt%) 12.5 4 <0.3 <0.3
U.C.S. by ASTM 24.63 24.55 24.48 24.38
NH3-TPD (mmol/g) - 0.7 2.0 1.3
Surface Area (BET, m2/g) 700 550 650 550
Crystal Size (µm) 0.2-0.4 0.2-0.4 0.7-1.0 0.2-0.4
Mean Particle Size (µm) 7-10 6-10 2-4 6-8

  341NHA 350HUA 360HUA 390HUA
Cation Type NH4 H H H
SiO2/Al2O3 (mol/mol) 7 10 15 200
Na2O (wt%) <0.2 <0.2 <0.1 <0.1
U.C.S. by ASTM 24.52 24.40 24.28 24.25
NH3-TPD (mmol/g) 2.0 1.1 0.1 <0.1
Surface Area (BET, m2/g) 700 650 600 750
Crystal Size (µm) 0.7-1.0 0.2-0.4 0.2-0.4 0.2-0.4
Mean Particle Size (µm) 2-4 6-8 6-8 6-8



HSZ® - 500 Series (L Zeolite)
  500KOA
Cation Type K
SiO2/Al2O3 (mol/mol) 6.0
Na2O (wt%) 0.2
K2O 17.0
Surface Area (BET, m2/g) 280
Crystal Size (µm) 0.2-0.4
Mean Particle Size (µm) 2-4



HSZ® - 600 Series (Mordenite)
  620HOA 640NAA
Cation Type H Na
SiO2/Al2O3 (mol/mol) 15 19
Na2O (wt%) 0.5 4.5
NH3-TPD (mmol/g) 2 -
Surface Area (BET, m2/g) 400 360
Crystal Size (µm) 1-3 0.1x 0.5
Mean Particle Size (µm) 15-20 10-12

  640HOA 660HOA 690HOA
Cation Type H H H
SiO2/Al2O3 (mol/mol) 19 30 200
Na2O (wt%) <0.1 <0.1 <0.05
NH3-TPD (mmol/g) 0.7 1.2 0.2
Surface Area (BET, m2/g) 380 400 420
Crystal Size (µm) 0.1x 0.5 0.1x 0.5 0.1x 0.5
Mean Particle Size (µm) 10-12 10-12 5-7



HSZ® - 700 Series (Ferrierite)
  720KOA
Cation Type K
SiO2/Al2O3 (mol/mol) 17.7
Na2O (wt%) 1.2
K2O 5.7
Surface Area (BET, m2/g) 170
Crystal Size (µm) …1
Mean Particle Size (µm) 20-30



HSZ® - 900 Series (Beta)
  930NHA 940NHA
Cation Type NH4 (containing TEMPLATE) NH4 (containing TEMPLATE)
SiO2/Al2O3 (mol/mol) 27 37
Na2O (wt%) <0.05 0.05
Surface Area (BET, m2/g) 630* 580*
Crystal Size (µm) 0.02-0.04 0.05
Mean Particle Size (µm) 3-6 6
*Pretreated in air at 650° C for 2 hours


For more information, please contact your nearest representative:

TOSOH Corporation TOSOH USA, Inc. TOSOH Europe B.V.
(Headquarters) (Head Office) (Head Office)
Shiba-koen First Bldg., 3600 Gantz Road, Crown Building-South,
3-8-2, Shiba, Minato-ku, Grove City, OH 43123-1895 Hullenbergweg 359,
Tokyo 105-8623, U.S.A. 1101 CP Amsterdam Z.O.,
Japan Tel: 1-614-277-4348 The Netherlands
Tel: 81-3-5427-5173 Tel: 1-866-844-6953 (U.S. Toll Free) Tel: 31-20-565-0010
Fax: 81-3-5427-5217 Fax: 1-614-875-8066 Fax: 31-20-691-5458
e-mail: info@tosoh.co.jp
URL: www.tosoh.com		 e-mail: info.tusa@tosoh.com
URL: www.tosohusa.com		 e-mail: info.tse@tosoh.com
URL: www.tosoh-europe.com