PRODUCTS

Battery Materials - EMD

The electrolytic manganese dioxide (EMD) industry has grown parallel with the dry battery industry. 

As a pioneer and a global leader of the EMD industry, Tosoh supplies EMD worldwide from its two production sites in Hyuga, Japan (Tosoh Hyuga Corporation) and Thessaloniki, Greece (Tosoh Hellas A.I.C.).


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Responding to the Growing Battery Materials Market

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Dry cell batteries are an essential product in our daily lives and in recent years their application has widely broadened to encompass a variety of portable electronic devices. Major developments which have contributed to the increase in battery demand and improvements in battery performance include:

  • Development of the portable transistor radio in the mid-1950's
  • Commercialization of the radio cassette player in the late 1960's
  • Market introduction of the headphone stereo in the late 1970's
  • Debut of the portable Game-Boy in the late 1980's
  • Development of the digital camera in the mid-1990's 
Tosoh's manganese business dates from 1925 when Tekkosha Co., Ltd (merged with Tosoh Corporation in 1975) was established to produce various ferroalloys, including ferromanganese, used in the steel industry. The company then focused on producing a substitute for imported battery-grade natural manganese dioxide using low-grade domestic ore, as autarchy was necessary in the early 1930's. After the trial production of synthetic manganese dioxide in 1932, the company went on to produce EMD in 1938, around the same period of the first commercial production of EMD in the United States.

The company resumed EMD production in 1953, after an interruption following the end of World War II. Since then, EMD has gradually replaced natural manganese dioxide, as its higher purity and quality was found to improve battery performance.

A new grass-roots EMD plant went on stream at Hyuga, in the southern part of Japan in 1965. In the plant, modern titanium cathodes were adopted instead of the carbon cathodes formerly used, in order to decrease impurities and improve the quality of the EMD. In 1975, Tosoh Hellas A.I.C., a joint venture with Mitsubishi Corporation, was established in Greece to supply EMD to the European market. With a total capacity of 52,000 tons/year, Tosoh Corporation is the proud leader in the EMD industry with a 20% share of the market. The company is strongly committed to a reliable supply and continuous improvement in the quality of its EMD.
   
Product Name: Electrolytic Manganese Dioxide (EMD)
Generic Name: Manganese Dioxide
Chemical Formula / Diagram: MnO2
Product Overview: Tosoh has one of the largest battery-grade EMD capacities in the world, with manufacturing facilities in both Japan and Greece. We are therefore readily able to meet the most demanding quantity requirements of our customers.
Applications: Dry Cells
Lithium Manganese Oxide
 

EMD Alkaline Battery Grades:

Chemical Properties  HH-P  HH-U 
Available Oxygen (as MnO2) (%)  91.0 min  91.0 min 
H2O (%)  2.0 max  2.0 max 
Fe (%)  0.02 max  0.02 max 
Cu (%) 
0.0005 max  0.0005 max 
Pb (%) 
0.0005 max  0.0005 max 
PH (%) 
6-7  6-7 
- 200 mesh (%) 
80.0 min  80.0 min 
- 325 mesh (%)     

Packaging:
Net 25, 40, and 50 kgs; polyethylene bag and paper bag

EMD Grades for LMO:

Grade LM05 LM10 LM25 
Particle 5µ  10µ 25µ 
D10 (µm) 2.1 3.1 9.0 
D50 (µm) 
5.1 9.7 24.0 
D90 (µm) 
8.4  21.2 42.4 
Mn (%) 
60.5 60.5 60.5 
S (ppm)
3,600 3,400 3,500 
Na (ppm) 170 160 200 
Fe (ppm)  34  35  37 
Cu (ppm)  <1  <1   <1  
Zn (ppm)  <1 
<1 
<1  
Pb (ppm)   <1 
<1 
<1  
       
   
Product Name: Brownox-X
Generic Name: Manganous Manganic Oxide
Chemical Formula / Diagram: Mn3O4
Product Overview: Widely regarded for their consistent purity and particle size, these highly purified reactive compounds are in growing demand for ferrite and thermistor applications. Tosoh has supplied manganous manganic oxide to electronics parts manufacturers for ferrite magnets since 1975.

Applications: Soft ferrites
Thermistors
 

Typical Properties / Grades:


Mn3O4
Mn (%)  70.0 min 
Moisture (%)  1.0 max 
SiO2 0.01 max 
CaO 
0.01 max 
Na
0.005 max